{"id":1095,"date":"2022-02-15T15:15:20","date_gmt":"2022-02-15T06:15:20","guid":{"rendered":"https:\/\/ds27i1.cc.yamaguchi-u.ac.jp\/~www-yu\/english\/?page_id=1095"},"modified":"2022-08-23T19:04:37","modified_gmt":"2022-08-23T10:04:37","slug":"izumi_kumakiri","status":"publish","type":"page","link":"https:\/\/ds27i1.cc.yamaguchi-u.ac.jp\/~www-yu\/english\/research\/cutting_edge_research\/izumi_kumakiri\/","title":{"rendered":"Exploring the Possibility of Membrane Separation Yamaguchi – Environmental Science and Engineering, Graduate School of Science and Engineering Associate Professor Izumi Kumakiri"},"content":{"rendered":"
Associate Prof. Kumakiri is working on the research field of the separation technology by using zeolite and carbon membranes. She aims at the developments of the unique and innovative technology by the combination use of the chemical reaction and the film separation methodology for hydrogen which is eco-friendly energy.<\/p>\n
Environmental Science and Engineering, I studied chemical engineering at university. My main research area is membrane science and technology. Membranes can separate mixtures by e.g. a sieving mechanism. Among various types of membranes, in particular I\u2019ve been working on nanoporous inorganic membranes, such as zeolite membranes and carbon membranes.<\/p>\n Our group \uff08Prof. Kita, Prof. Tanaka, and I\uff09 has been involved in national research and development projects targeting to develop a hydrogen carrier system and an artificial photosyn-thesis system by applying hydrogen-selective membranes. Although hydrogen has attracted attention as an environmen-tally friendly energy source, stable supply of large amount of hydrogen is one of the major challenges. Electrolysis of water using renewable energy is one way of producing hydrogen. Some companies are considering using cheap renewable energy in abroad, e.g. solar power generation in Australia and wind power generation in Chile, to produce hydrogen, and transport-ing hydrogen in the form of methylcyclohexane\u0336a liquid chemical substance at room temperature\u0336by tankers or other vessels. At the end-users, e.g. at hydrogen stations, methylcy-clohexane is decomposed to hydrogen and toluene by dehydro-genation reaction, followed by a separation process to take out hydrogen. Membrane separation is a promising innovative technology due to its simple operation, small footprint of the unit and low energy-requirement. We are working on the devel-opment of new types of membranes for hydrogen separation. In artificial photosynthesis, photocatalysts split water into hydro-gen and oxygen gases. However, a mixture of these two kinds of gas is explosive under a certain composition range. As membranes can separate hydrogen at room temperature continuously, combination of photocatalysis and membrane separation will reduce the risk of explosion. As shown above with two examples, we believe membrane technology is one of the key processes in the realization of a hydrogen society.<\/p>\n Agreements between Yamaguchi University and the University of Zaragoza, Universidade NOVA de Lisboa, and the University of Cantabria have been signed.<\/strong><\/p>\n These agreements allow students to take classes at partner universities. We also organized international symposiums with these partner universities. In 2014, the second symposium was held in Ube, where Tokiwa campus is located. In 2016, we will have third symposium in Lisbon.<\/p>\n<\/div>\n Prof. Mamoru Yamada of the Faculty of Agriculture at Yama-guchi University is studying fermentation using unique medium-to-high temperature\u2012resistant microorganisms. Fermentation broth contains a variety of substances, therefore separation process is required to take out the substance required. For example, bioethanol is regarded as a green fuel and replacing gasoline in some countries. Generally the ethanol concentration in the fermented broth is about 5-10%. The ethanol concentration should be over 99.5% to use bio-ethanol as a fuel additive. Conventional distillation process has a high energy demand, especially to overcome the azeotrope. On the contrary membrane separation process has no limitation of azeotrope and can drastically reduce the energy required for separation. Collaboration with the Faculty of Agriculture is expected to bring ideas of new technologies, such as simultane-ous fermentation and separation for higher efficient reactors.<\/p>\n Membrane reactors are new concepts where membranes and chemical reactions are combined. This innovative concept is expected to reduce the size of a reactor, improve conversion, and lower the temperature\/pressure of the reaction. Therefore, research on membrane reactors has been accelerating. The advantage of this concept is demonstrated with thermodynami-cally dominated reactions. As membranes can take out one \uff08or more\uff09 of the products from the reaction field, higher conver-sion than the equilibrium limited value can be achieved.For example, combining a zeolite membrane to an esterification reaction improves the conversion, as the membrane removes produced water simultaneously from the reaction field that sifts the equilibrium. Water gas shift reaction is another thermodynamically limited reaction. In this case, removing either hydrogen or carbon dioxide shifts the reaction. However, high temperature over ca. 500 \u00baC is required. We are working on inorganic sorbents and membranes to separate carbon dioxide at high temperature.<\/p>\n
\nGraduate School of Science and EngineeringAssociate Professor
\nIzumi KUMAKIRI<\/span><\/strong><\/p>\n<\/div>\n\n
\n 2014:<\/td>\n Associate Professor at Graduate School of Science and Engineering, Yamaguchi University<\/td>\n<\/tr>\n \n 2011:<\/td>\n Assistant Professor at Graduate School of Science and Engineering, Yamaguchi University<\/td>\n<\/tr>\n \n 2006<\/td>\n Visiting scientist at Arizona State University, USA<\/td>\n<\/tr>\n \n 2004:<\/td>\n Full-time researcher at SINTEF, Oslo, Norway<\/td>\n<\/tr>\n \n 2004:<\/td>\n Visiting scientist at University of Cincinnati, USA<\/td>\n<\/tr>\n \n 2002:<\/td>\n Project researcher at SINTEF, Oslo, Norway<\/td>\n<\/tr>\n \n 2000:<\/td>\n Research fellow at Centre National de la Recherche Scientifique, Institut de Recherches sur la Catalyse \uff08CNRS-IRC, IRCELYON\uff09, Villeurbanne, France<\/td>\n<\/tr>\n \n 2000:<\/td>\n Ph.D., Department of Chemical System Engineering, Graduate School of Engineering, the University of Tokyo<\/td>\n<\/tr>\n \n 1994:<\/td>\n Graduated from Faculty of Engineering, the University of Tokyo<\/td>\n<\/tr>\n<\/table>\n<\/div>\n<\/div>\n Zeolite membranes and carbon membranes contributing to the green technology<\/h4>\n
Column<\/h4>\n
Research collaborations with the Faculty of Agriculture<\/h4>\n
Increasing chemical reaction efficiency by using membrane separation technology<\/h4>\n